Organic matter strongly influences the behaviour of dissolved metals in nat
ural waters. A complete understanding on the nature of these compounds, req
uires their isolation. The most recently used extraction procedure is rever
se-phase liquid chromatography, or solid phase extraction (SPE), by which r
esins are supposed to retain hydrophobic dissolved material. However, no st
udies have been done coupling this method with sequential tangential ultraf
iltration (STUF). For this purpose two types of ultrafiltered natural sampl
es from the Amazonian River system were used. First, to determine if these
two extractive methods are complementary, and second, to compare the effici
ency of two SPE methods according to particle size, and amount. (C) 2000 El
sevier Science Ltd. All rights reserved.