J. Lee et al., Toward creation of a universal NMR database for the stereochemical assignment of acyclic compounds: Proof of concept, ORG LETT, 1(13), 1999, pp. 2181-2184
Using the C.5-C.10 portion of the oasomycin class of natural products, the
reliability and usefulness of an NMR database for the stereochemical assign
ment of acyclic compounds has been demonstrated. The predicted relative ste
reochemistry based on the NMR database has unambiguously been established v
ia synthesis.