The effect of alkaline earth metal oxide on nickel catalyst for carbon dioxide reforming of methane

Citation
Ks. Jung et al., The effect of alkaline earth metal oxide on nickel catalyst for carbon dioxide reforming of methane, RES CHEM IN, 26(1), 2000, pp. 45-53
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RESEARCH ON CHEMICAL INTERMEDIATES
ISSN journal
09226168 → ACNP
Volume
26
Issue
1
Year of publication
2000
Pages
45 - 53
Database
ISI
SICI code
0922-6168(2000)26:1<45:TEOAEM>2.0.ZU;2-F
Abstract
A study on the effect of alkaline earth metal oxide on the activity and sta bility of nickel catalyst for carbon dioxide reforming of methane was perfo rmed. When CaO, SrO, and BaO were used as supports, there was no difference in catalytic activity between the catalysts made by coprecipitation and im pregnation. However, when MgO was used as a support, the catalyst prepared by coprecipitation showed superior activity than that made by impregnation. The higher activity of the catalyst made by coprecipitation was due to the formation of solid solution consisting of nickel and magnesium. The format ion of the solid solution enhanced the dispersion of nickel and the resista nce to coke formation.