A new, lightweight balloon-borne instrument (DESCARTES) has been developed
to make measurements of long-lived trace gases in the stratosphere. DESCART
ES is designed to be simple to operate and to fly on small balloons or to "
piggyback" on larger payloads. To collect samples, a measured volume of air
is passed through a sample tube containing a Carboxen adsorbent. Atmospher
ic halocarbons are adsorbed and the sample tube is then isolated under an i
nert nitrogen atmosphere. A number of sample tubes are filled at different
altitudes during the flight. After recovery of the instrument the halocarbo
ns are thermally desorbed and quantified using a gas chromatograph with an
electron capture detector. In this article we present the design, test, and
operation of the instrument with particular emphasis on CFC-11 (CFCl3), th
e gas for which operation has been optimized. (C) 2000 American Institute o
f Physics. [S0034-6748(99)01712-8].