The red luminescence at 686 nm in KTaO3 has been investigated in pure as-gr
own, ultra-high purity and doped (Al, Ba, Cr, Fe, Er, Li, Mg, Ni, Ph, V, Cr
, Zr) crystals from different growth laboratories. In contrast to earlier r
esults [P. Grenier, G. Bernier, S. Jandl, B. Salce, L.A. Boatner, J. Phys.:
Cond. Matt 1(1989) 2515; P. Grenier, S. Jandl, M. Blouin, L.A. Boatner, Fe
rroel. 137 (1992) 105] which led to the conclusion that the main center sho
uld be an intrinsic defect Ta3+ + O2- vacancy, we found a strong dependence
on any kind of heat treatment (oxidation or reduction) leading to a decrea
sing or vanishing of the red luminescence after these treatments. The red l
uminescence was found to be sample dependent, together with a dependence on
growth procedure. Therefore, excited metastable defect states which can be
quenched in the same manner by reduction or oxidation treatments, have to
be discussed as the origin of the red luminescence. The (i) two hole polaro
ns localised near a Ta3+ (ii) Ta3+-O-0-center (a vibronic exciton with doub
le charge transfer) and at last (iii) a pair of Ta3+, one in a Ta5+ site an
d the other in a K+ site are discussed as possible centers connected with t
he red luminescence. (C) 2000 Published by Elsevier Science Ltd. All rights
reserved.