This tutorial survey describes the application of selected photon- and elec
tron-excited characterisation techniques for the analysis of thin films. Th
e fundamentals of some techniques are discussed but the focus of this artic
le is the link between the different techniques rather than a comprehensive
discussion of them. Laboratory-based and synchrotron radiation techniques
are compared for the characterization of long- and short-range structural o
rder, as well as for chemical and electronic structural analysis. The pract
ical application of the analytical procedures discussed is summarized in tw
o case studies. Copyright (C) 2000 John Wiley & Sons, Ltd.