Palladium catalyzed reaction of alpha-chloromethylnaphthalene with olefins

Authors
Wang, LS Pan, Y Jiang, X Hu, HW
Citation
Ls. Wang et al., Palladium catalyzed reaction of alpha-chloromethylnaphthalene with olefins, TETRAHEDR L, 41(5), 2000, pp. 725-727
Citations number
8
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
5
Year of publication
2000
Pages
725 - 727
Database
ISI
SICI code
0040-4039(20000129)41:5<725:PCROAW>2.0.ZU;2-S
Abstract
The reaction of alpha-chloromethylnaphthalene with various olefins in the p resence of palladium acetate produces three different kinds of products. Th e coupling products with the olefinic bond conjugated to the naphthalene ri ng are the major products for the reactions of most olefins. An unusual rea rrangement product formed via a cyclopalladation intermediate is isolated f rom the reactions of the two N-vinyl olefins. (C) 2000 Elsevier Science Ltd . All rights reserved.