We have studied the how of a non-aqueous phase liquid (NAPL, or oil),
water and air at the pore scale using a micromodel. The pore space pat
tern from a photomicrograph of a two-dimensional section through a Ber
ea sandstone was etched onto a silicon wafer. The sizes of the pores i
n the micromodel are in the range 3-30 mu m and are the same as observ
ed in the rock from which the image was taken. We conducted three-phas
e displacement experiments at low capillary numbers (in the order of 1
0(-7)) to observe the presence of predicted displacement mechanisms at
the pore scale. We observed stable oil layers between the wetting pha
se (water) and the non-wetting phase (gas) for the water-decane-air sy
stem, which has a negative equilibrium spreading coefficient, as well
as four different types of double displacements where one fluid displa
ces another that displaces a third. Double imbibition and double drain
age are readily observed, but the existence of an oil layer surroundin
g the gas phase makes the other double displacement combinations very
unlikely.