The morphology and surface structures of silicon nitride films grown on Si(
111) by exposing to ammonia at high temperature have been systematically st
udied using scanning tunneling microscopy. The results showed that flat bet
a-Si3N4 crystalline films could be obtained at a nitridation temperature of
1075-1275 K. A (4 x 4) reconstruction of beta-Si3N4 (0001) was observed on
the nitride film.