Zy. Zhong et al., Preparation of mesoscale hollow spheres of TiO2 and SnO2 by templating against crystalline arrays of polystyrene beads, ADVAN MATER, 12(3), 2000, pp. 206
Mesoscale hollow spheres of ceramic materials can be prepared by templating
an appropriate sol-gel precursor against a crystalline array of monodisper
se polystyrene beads, as demonstrated here. Spheres of well-controlled, uni
form size and homogeneous wall thickness result, as can be seen from the Fi
gure, which shows the TEM cross-sectional view of an array of TiO2 hollow s
pheres.