MOLECULAR ADDUCTS OF INORGANIC SALTS .7. CADMIUM TETRAOXORHENIUM HEXAKIS(THIOUREA) HYDRATE

Authors
PETROVA R ANGELOVA O MACICEK J
Citation
R. Petrova et al., MOLECULAR ADDUCTS OF INORGANIC SALTS .7. CADMIUM TETRAOXORHENIUM HEXAKIS(THIOUREA) HYDRATE, Acta crystallographica. Section C, Crystal structure communications, 53, 1997, pp. 565-568
Citations number
18
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
53
Year of publication
1997
Part
5
Pages
565 - 568
Database
ISI
SICI code
0108-2701(1997)53:<565:MAOIS.>2.0.ZU;2-9
Abstract
The title compound, [Cd(CH4N2S)(6)](ReO4)(2).H2O, is built up of isola ted centrosymmetric [Cd{SC(NH2)(2)}(6)](2+) octahedra, ReO4- tetrahedr a and water molecules packed most densely in the ac plane. Two of the three nonequivalent thiourea molecules are almost parallel and the thi rd one is perpendicular to the ac plane. The structural units are held together by a complex network of intra-and intercluster hydrogen bond s.