Real-time probing of elementary charge transfer processes in liquids and solutions

Authors
Citation
Y. Gauduel, Real-time probing of elementary charge transfer processes in liquids and solutions, B POL CHEM, 47(4), 1999, pp. 303-331
Citations number
202
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY
ISSN journal
02397285 → ACNP
Volume
47
Issue
4
Year of publication
1999
Pages
303 - 331
Database
ISI
SICI code
0239-7285(1999)47:4<303:RPOECT>2.0.ZU;2-O
Abstract
With the intensive development of ultrafast spectroscopic methods, the cour se of elementary reactions may be observable on the time scale of molecular motions. The femtosecond solution chemistry allows the real-time probing o f solvent cage effects during charge transfers. Recent studies devoted to t he understanding of electron dynamics in liquid phase are presented and dis cussed in the framework of quantum theories on nonequilibrium electronic st ates. This progress provides guidance for further research works on the mic roscopic description of reactional processes occurring in complicated many body systems.