The O-specific side-chain polymers from Stenotrophomonas maltophilia serogr
oups O21 and O25 were isolated from the lipopolysaccharides of the referenc
e strains. The O21 polymer contained D-arabinose, 2-amino-2-deoxy-D-glucose
and 2-amino-2-deoxy-D-galactose in equal proportions. Methylation analysis
and NMR spectroscopy showed that the polysaccharide is based on a branched
trisaccharide repeating unit of the structure shown below. The O25 polymer
is linear with a disaccharide repeating unit identical to that forming the
backbone of the O21 polymer.
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