The paper discusses some rather non-traditional uses of polarography and vo
ltammetry which are beyond common polarographic routine in analytical labor
atories. Some potentials of polarography in the biological and biochemical
fields are treated spanning from in vivo measurements to sensors for diagno
stic purposes in medicine and toxicology. Examples are given of analyses in
the solid and gas phases as well as the use in tribodiagnostics in determi
nation of machine wear.