S. Desai et al., Effect of polyols and diisocyanates on thermo-mechanical and morphologicalproperties of polyurethanes, EUR POLYM J, 36(4), 2000, pp. 711-725
Polyurethanes based on two polyols PPG (polypropylene glycol) and HTPB (hyd
roxy terminated polybutadiene) and diisocyanates TDI (toluene diisocyanate)
and MDI (methylene diphenyl diisocyanate) were synthesised using three dif
ferent concentrations of the crosslinker 1,1,1-trimethylolpropane (TMP) at
NCO : OH equivalent ratio 1.2 and 1.3. The mechanical, thermal and morpholo
gical properties were investigated. HTPB/TDI system showed highest tensile
strength whereas PPG/MDI system exhibited highest elongation at break, In d
ifferential scanning calorimetry (DSC) thermograms transition for soft segm
ent was observed to be considerably higher in PPG based polyurethanes (PUs)
. The dielectric constant was also found to be higher in PPG based PUs. The
tan delta(max) was found to lie in the range 0.7-1.0. From swelling behavi
our the solubility parameter for PPG and HTPB based PUs was found to be 9.7
and 8.6 (cal/cm(3))(1/2), respectively. The molecular weight between cross
links were determined by using the Flory-Rehner equation. (C) 2000 Elsevier
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