A. Kubaczka et A. Burghardt, Effect of the individual mass transport resistances on the overall mass fluxes in multicomponent systems, INZ CHEM PR, 20(4), 1999, pp. 561-584
The method to assess the relative importance of the individual mass transpo
rt resistances has been developed for multicomponent systems where each of
the constituent resistance is defined by an appropriate matrix of mass tran
sfer coefficients. This method is validated using multicomponent membrane e
xtraction as a test case. The process is both energy-efficient and easy to
operate. The process was studied experimentally as a test case. The effect
of all the individual mass transport mechanisms on the overall mass fluxes
is studied.
If resistances to mass transfer, identified by the method as insignificant,
are omitted from the simulations, the agreement between numerical predicti
ons and the experiment is not impaired. It is also demonstrated that the ac
curacy of calculating mass fluxes in membrane extractors became worse when
the variation of diffusivities with concentration along the diffusion path
is neglected, and also, when the effect of the membrane on interrelationshi
ps between the mass fluxes (referred to the stationary system of co-ordinat
es) is not taken into account.