The magnetic phase diagrams of S = 1/2 axial third-nearest-neighbour Ising
(A3NNI) model under an external field have been studied by means of the mol
ecular field approximation. The phase boundaries among paramagnetic, (anti)
ferromagnetic and various modulated phases are determined by analysing the
frequency-dependent susceptibility, or by solving the coupled equations fo
r magnetisations for spins up to 17, iteratively. The resultant phase diagr
am is found to be very consistent with the exact results for the ground sta
te spin ordering and to be far improved than existing finite temperature ph
ase diagrams for the same model. (C) 2000 Elsevier Science B.V. All rights
reserved.