Ni, NiO and LixNi1-xO are the cathodic materials commonly used in molten ca
rbonate fuel cells (MCFCs). Since the instability of the cathode is recogni
zed as a major hindrance to MCFC development, in this report the behaviour
of these nickel species in molten alkali carbonates is reviewed, analyzing
step by step the processes of lithiation, dissolution and sinterization at
cell operating temperatures. (C) 2000 Kluwer Academic Publishers.