Kb. Shim et al., Silver diffusion and microstructure in LTCC multilayer couplers for high frequency applications, J MATER SCI, 35(4), 2000, pp. 813-820
Low temperature cofired glass ceramic-Ag metal electrode (LTCC) systems wer
e investigated in relation to Ag diffusion and microstructural development
in the fabrication of high frequency couplers. Sintering temperature was in
a range of 825 degrees C-975 degrees C. Ag diffusion was not observed belo
w 875 degrees C but densification of the electrode was greatly improved. At
higher temperature above 900 degrees C, Ag ions were diffused through glas
s phases containing Pb and alkali ions. Crystalline phases behaved as a bar
rier for the Ag diffusion. With increasing sintering temperature, glass inf
iltration to the electrode also occurred due to increased fluidity of the g
lass phase and the electrode line were severely deformed and damaged. (C) 2
000 Kluwer Academic Publishers.