Photosensitive cholesteric copolymers with spiropyran-containing side groups - II. Kinetic features of the photo- and thermo-chromic processes

Citation
Ak. Bobrovsky et al., Photosensitive cholesteric copolymers with spiropyran-containing side groups - II. Kinetic features of the photo- and thermo-chromic processes, LIQ CRYST, 27(2), 2000, pp. 219-223
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
27
Issue
2
Year of publication
2000
Pages
219 - 223
Database
ISI
SICI code
0267-8292(200002)27:2<219:PCCWSS>2.0.ZU;2-T
Abstract
Kinetic features of the photo- and thermo-chromic behaviour of new choleste ric triple copolymers with photosensitive spiropyran-containing side groups are considered. The kinetics of the back thermal process at different temp eratures have been studied; activation energies for this process for the co polymers with different contents of the dye units have been obtained. The p hotochromic homopolymer and copolymers with a low content of dye units are shown to possess maximum values of the activation energy.