FREE-RADICAL MEDIATED CONSTRUCTION OF SMALL RING COMPOUNDS - THE DOUBLE ANNULATION OF BICYCLO[3.1.0]HEX-2-ENES

Citation
Z. Ferjancic et al., FREE-RADICAL MEDIATED CONSTRUCTION OF SMALL RING COMPOUNDS - THE DOUBLE ANNULATION OF BICYCLO[3.1.0]HEX-2-ENES, Tetrahedron letters, 38(23), 1997, pp. 4165-4168
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
23
Year of publication
1997
Pages
4165 - 4168
Database
ISI
SICI code
0040-4039(1997)38:23<4165:FMCOSR>2.0.ZU;2-3
Abstract
A free radical approach to fused cyclopropane derivatives is described . Homolytic decomposition of thiohydroxamic esters 4a-e in the presenc e of dimethyl acetylendicarboxylate affords bicyclo[3.1.0]hex-2-enes 6 a-e in moderate yields. (C) 1997 Elsevier Science Ltd.