Palladium-catalyzed cross-coupling reactions of triorganoindium compounds with vinyl and aryl triflates or iodides

Authors
Perez, I Sestelo, JP Sarandeses, LA
Citation
I. Perez et al., Palladium-catalyzed cross-coupling reactions of triorganoindium compounds with vinyl and aryl triflates or iodides, ORG LETT, 1(8), 1999, pp. 1267-1269
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
8
Year of publication
1999
Pages
1267 - 1269
Database
ISI
SICI code
1523-7060(19991021)1:8<1267:PCROTC>2.0.ZU;2-D
Abstract
[GRAPHICS] A novel palladium-catalyzed cross coupling reaction of organoindium compoun ds with vinyl and aryl triflates or iodides is described. The reaction proc eeds for alkyl-, vinyl-, alkynyl-, and arylindium compounds in excellent yi elds and high chemoselectivity without any excess of the organometallic. Re markably, indium organometallics transfer efficiently the three organic gro ups attached to the metal.