ROMP-spheres: A novel high-loading polymer support using cross metathesis between vinyl polystyrene and norbornene derivatives

Authors
Barrett, AGM Cramp, SM Roberts, RS
Citation
Agm. Barrett et al., ROMP-spheres: A novel high-loading polymer support using cross metathesis between vinyl polystyrene and norbornene derivatives, ORG LETT, 1(7), 1999, pp. 1083-1086
Citations number
29
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
7
Year of publication
1999
Pages
1083 - 1086
Database
ISI
SICI code
1523-7060(19991007)1:7<1083:RANHPS>2.0.ZU;2-M
Abstract
[GRAPHICS] The preparation of a polymer-supported ruthenium alkylidene metathesis cata lyst is described. This immobilized catalyst has been used to initiate a ri ng-opening metathesis polymerization of norbornene derivatives onto a polym er support to prepare novel high-loading resins for use in combinatorial ch emistry.