Metalation of iminium ions formed in the reaction of tertiary amines with TiCl4

Authors
Bharathi, P Periasamy, M
Citation
P. Bharathi et M. Periasamy, Metalation of iminium ions formed in the reaction of tertiary amines with TiCl4, ORG LETT, 1(6), 1999, pp. 857-859
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
6
Year of publication
1999
Pages
857 - 859
Database
ISI
SICI code
1523-7060(19990923)1:6<857:MOIIFI>2.0.ZU;2-W
Abstract
[GRAPHICS] TiCl4 reacts with trialkylamines at 0-25 degrees C to give iminium ions tha t on metalation followed by reaction with diaryl ketones, produce alpha,bet a-unsaturated aldehydes.