Citation
Q. Zhu et al., Radical-mediated diastereoselective construction of a chiral synthon for synthesis of dolabellanes, ORG LETT, 1(5), 1999, pp. 757-759
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060
→ ACNP
Volume
1
Issue
5
Year of publication
1999
Pages
757 - 759
Database
ISI
SICI code
1523-7060(19990909)1:5<757:RDCOAC>2.0.ZU;2-#
Abstract
[GRAPHICS]
A useful trans substituted multifunctional cyclopentane with a chiral quate
rnary center was selectively synthesized by free radical Michael addition t
o the (Z)-propionate or malonate derivatives. The stereoselectivity could b
e reversed by changing the configuration of the double bond.