Solid-phase oligosaccharide synthesis: Preparation of complex structures using a novel linker and different glycosylating agents

Citation
Rb. Andrade et al., Solid-phase oligosaccharide synthesis: Preparation of complex structures using a novel linker and different glycosylating agents, ORG LETT, 1(11), 1999, pp. 1811-1814
Citations number
50
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
11
Year of publication
1999
Pages
1811 - 1814
Database
ISI
SICI code
1523-7060(199912)1:11<1811:SOSPOC>2.0.ZU;2-W
Abstract
[GRAPHICS] A beta-(1-->4) linked trisaccharide was prepared in 53% yield on a polymer support using glycosyl phosphates and released by cross-metathesis of a nov el linker to reveal the anomeric n-pentenyl glycoside. Heptasaccharide 33 w as prepared in 9% yield in 14 steps.