Convergent synthesis of p-benzylcalix[7]arene: Condensation and UHIG of p-benzylcalix[6 or 8]arenes

Authors
Atwood, JL Hardie, MJ Raston, CL Sandoval, CA
Citation
Jl. Atwood et al., Convergent synthesis of p-benzylcalix[7]arene: Condensation and UHIG of p-benzylcalix[6 or 8]arenes, ORG LETT, 1(10), 1999, pp. 1523-1526
Citations number
34
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
1
Issue
10
Year of publication
1999
Pages
1523 - 1526
Database
ISI
SICI code
1523-7060(19991118)1:10<1523:CSOPCA>2.0.ZU;2-C
Abstract
[GRAPHICS] p-Benzylcalix[5]arene and p-benzylcalix[7]arene are formed on ultrahigh int ensity grinding (UHIG) of p-benzylcalix[6 or 8]arenes in the presence of KO H and molecular sieves (4 Angstrom), and the same calix[7]arene is also for med on condensation of p-benzylphenol and formaldehyde (15-20% yield), unde r more forcing conditions, along with p-benzylcalix[10]arene.