A class of meson decay modes sensitive to only one quark topology at leadin
g C-F Order (annihilation of valence quarks through a W) is described. No e
xperimental observations, or even upper limits, have been reported for thes
e decays. This work presents a simpleminded (order-of-magnitude) calculatio
n of their branching fractions, and compares to results of previous calcula
tions where available. Although rare, one of these modes (D-s(+) --> rho(+)
gamma) might already be observable at charm experiments; two others (D+ --
> K*(+) gamma, B+ --> D-s*(+) gamma) should appear at the B factories, and
the rest at hadron colliders.