New techniques for remote sensing of solar magnetic fields now provide meas
ures of the magnetic field vector within the solar atmosphere with high ang
ular resolution and high precision. These measurements have enabled a much
improved physical understanding of magnetic processes and phenomena in the
solar atmosphere, processes that drive the variability of the Sun's radiati
ve and particulate output. The new techniques are reviewed here in the cont
ext of the scientific advances they have fostered. Emphasis is given to tec
hniques for inferring the field vector. The quantitative nature of the info
rmation needed to explore the solar phenomena sharply constrains the needed
precision and angular resolution of the observations. These requirements a
re reviewed here, along with an assessment of how future improvements in ob
serving capabilities will address these requirements. One may also attribut
e much of the recent advance in our understanding of solar magnetic fields
to ongoing progress in techniques for analysis of the polarization measurem
ents that underlie solar magnetometry. The status and prospects of analysis
techniques are also reviewed.