A GENERAL-SYNTHESIS OF AMINES AND HYDRAZINES BY OXIDATION OF AMIDOCUPRATES AND ZINC-AMIDOCUPRATES

Authors
CANE F BRANCALEONI D DEMBECH P RICCI A SECONI G
Citation
F. Cane et al., A GENERAL-SYNTHESIS OF AMINES AND HYDRAZINES BY OXIDATION OF AMIDOCUPRATES AND ZINC-AMIDOCUPRATES, Synthesis, (5), 1997, pp. 545
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
5
Year of publication
1997
Database
ISI
SICI code
0039-7881(1997):5<545:AGOAAH>2.0.ZU;2-J
Abstract
A wide range of amines and hydrazines were synthesized according to an electrophilic amination protocol by oxidative decomposition of readil y generated lithium- and zinc-amidocyanocuprates. Optimization of the yields was achieved by the appropriate combination of the organometall ic cluster and the nature of the oxidizing agent.