The synthesis of novel chiral N,O-ferrocenyl ligands and their applicationin the addition of diethylzinc to aldehydes

Authors
Deng, WP Hou, XL Dai, LX
Citation
Wp. Deng et al., The synthesis of novel chiral N,O-ferrocenyl ligands and their applicationin the addition of diethylzinc to aldehydes, TETRAHEDR-A, 10(24), 1999, pp. 4689-4693
Citations number
13
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON-ASYMMETRY
ISSN journal
09574166 → ACNP
Volume
10
Issue
24
Year of publication
1999
Pages
4689 - 4693
Database
ISI
SICI code
0957-4166(199912)10:24<4689:TSONCN>2.0.ZU;2-S
Abstract
Novel chiral N,O-ferrocenyl ligands, in which N and O groups were attached to two different Cp rings of ferrocene, were synthesized from easily availa ble ferrocene, and applied to the asymmetric diethylzinc addition to aldehy des. High chemical yields and good enantioselectivities (up to 90.9% ee) we re obtained by using ferrocene ligand 6. (C) 2000 Published by Elsevier Sci ence Ltd. All rights reserved.