[Cd(4,4 '-bipy)(2)(NO3)(2)](2-nitroaniline)2, a novel two-dimensional lattice inclusion compound

Authors
Huang, SPD Lewandowski, BJ Liu, CB Shan, YK
Citation
Spd. Huang et al., [Cd(4,4 '-bipy)(2)(NO3)(2)](2-nitroaniline)2, a novel two-dimensional lattice inclusion compound, ACT CRYST C, 55, 1999, pp. 2016-2018
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
12
Pages
2016 - 2018
Database
ISI
SICI code
0108-2701(199912)55:<2016:['ANTL>2.0.ZU;2-4
Abstract
In the title complex, poly[[[bis(nitrato-O)cadmium(II)]bis(mu-4,4'-bipyridy l-N:N')] bis(2-nitroaniline)], [Cd(NO3)(2)(C10H8N2)(2)]. 2C(6)H(6)N(2)O(2), octahedrally coordinated Cd2+ ions are connected by linear rigid 4,4'-bipy ridine ligands to form infinite two-dimensional square grids with the nitra te anions occupying the axial positions. The 2-nitroaniline guest molecules fill the space between the grids through pi-pi stacking interactions. The average Cd-N and Cd-O bond distances are 2.347 (3) and 2.352 (3) Angstrom, respectively.