(Acetonitrile-N)(eta(4)-2-methylbuta-1,3-diene)(eta(5)-pentamethylcyclopentadienyl)-ruthenium(II) trifluoromethanesulfonate

Authors
Gemel, C Kirchner, K Schmid, R Mereiter, K
Citation
C. Gemel et al., (Acetonitrile-N)(eta(4)-2-methylbuta-1,3-diene)(eta(5)-pentamethylcyclopentadienyl)-ruthenium(II) trifluoromethanesulfonate, ACT CRYST C, 55, 1999, pp. 2053-2055
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
12
Pages
2053 - 2055
Database
ISI
SICI code
0108-2701(199912)55:<2053:(>2.0.ZU;2-G
Abstract
The title compound, [Ru{eta(5)-C-5(CH3)(5)}{eta(4)-CH2C(CH3)CHCH2}(CH3CN)]( CF3SO3) or [Ru(C5H8)(C10H15)(C2H3N)](CF3SO3), contains a half-sandwich ruth enium complex with an exo-oriented pi-bonded diene moiety inclined at an an gle of 16.0(2)degrees to the cyclopentadienyl ring. The coordination geomet ry of ruthenium can be described as a three-legged piano stool.