Mirror symmetry in 7,9-dibenzyl-1-tert-butoxycarbonyl-1,7,9-triazaspiro[4.5]dec-3-en-2-one

Authors
Dong, YK Yun, HS Suh, JM Ahn, YG Ha, HJ
Citation
Yk. Dong et al., Mirror symmetry in 7,9-dibenzyl-1-tert-butoxycarbonyl-1,7,9-triazaspiro[4.5]dec-3-en-2-one, ACT CRYST C, 55, 1999, pp. 2088-2090
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
12
Pages
2088 - 2090
Database
ISI
SICI code
0108-2701(199912)55:<2088:MSI7>2.0.ZU;2-7
Abstract
The crystal structure of tert-butyl 7,9-dibenzyl-2-oxo-1,7,9-triazaspiro[4. 5]dec-3-ene-1-carboxylate, C26H31N3O3, is reported. The molecule has impose d mirror symmetry and the hexahydropyrimidine ring adopts a chair conformat ion with two benzyl substituents bonded equatorially to the ring N atoms. T he 3-pyrrolin-2-one is attached as a spiro-skeleton to the hexahydropyrimid ine ring by one axial C-C and one equatorial C-N bond.