Intersite transfer of industrial calibration models

Citation
F. Despagne et al., Intersite transfer of industrial calibration models, ANALYT CHIM, 406(2), 2000, pp. 233-245
Citations number
23
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
ANALYTICA CHIMICA ACTA
ISSN journal
00032670 → ACNP
Volume
406
Issue
2
Year of publication
2000
Pages
233 - 245
Database
ISI
SICI code
0003-2670(20000221)406:2<233:ITOICM>2.0.ZU;2-V
Abstract
Two instrument standardisation methods, the piecewise direct standardisatio n and a method based on neural networks, are compared for the transfer of i ndustrial near-infrared powder spectra between two sites. Some important is sues that can affect transfer, such as influence of signal preprocessing or representativity of standardisation samples are discussed in detail. Parti cularities and limitations specific to each transfer method are outlined. I n particular, it is shown that both methods lead to different reconstructio n results in the presence of structured background noise. (C) 2000 Elsevier Science B.V. All rights reserved.