Complete end-capping during the copolymerization of trioxane and ethylene oxide

Citation
H. Nagahara et al., Complete end-capping during the copolymerization of trioxane and ethylene oxide, CHEM LETT, (1), 2000, pp. 2-3
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
1
Year of publication
2000
Pages
2 - 3
Database
ISI
SICI code
0366-7022(20000105):1<2:CEDTCO>2.0.ZU;2-1
Abstract
Complete end-capping during the copolymerization of trioxane and ethylene o xide in the bulk polymerization state using boron trifluoride dibutyl ether as the initiator and methylal as the chain transfer agent was accomplished . By using highly purified trioxane as the starting material and by complet ely deactivating the catalyst residue, an almost completely end-capped poly mer (degree of stability was over 99.5%) was obtained.