The Co-2(CO)(8)-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

Authors
Chatani, N Kodama, T Kajikawa, Y Murakami, H Kakiuchi, F Ikeda, S Murai, S
Citation
N. Chatani et al., The Co-2(CO)(8)-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step, CHEM LETT, (1), 2000, pp. 14-15
Citations number
24
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
1
Year of publication
2000
Pages
14 - 15
Database
ISI
SICI code
0366-7022(20000105):1<14:TCHOOO>2.0.ZU;2-8
Abstract
The hydrosilylation of oxygen-containing olefins in the presence of Co-2(CO )(8) was carried out. The Co-2(CO)(8)-catalyzed hydrosilylation of allyl ac etate with HSiEt2Me is consistent with proceeding via a silylmetalation mec hanism rather than a classical hydrometalation (Chalk-Harrod mechanism).