A composite Na+ conductor of polycrystalline NASICON mixed with a glassy Na
2O-Al2O3-4SiO(2) (40wt%) was used in Cl-2 gas sensor. The probe using the c
omposite electrolyte and a RuO2+NaCl (1:1) measuring electrode gave rapid E
MF changes even for sub-ppm level of Cl-2 gas concentration (below 6 ppm).