Syntheses and structures of trimethylphosphine-complexed primary boryl complexes of group 8 metals, Cp*M(CO)(2)(BH2 center dot PMe3) (M = Fe, Ru)

Authors
Yasue, T Kawano, Y Shimoi, M
Citation
T. Yasue et al., Syntheses and structures of trimethylphosphine-complexed primary boryl complexes of group 8 metals, Cp*M(CO)(2)(BH2 center dot PMe3) (M = Fe, Ru), CHEM LETT, (1), 2000, pp. 58-59
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
1
Year of publication
2000
Pages
58 - 59
Database
ISI
SICI code
0366-7022(20000105):1<58:SASOTP>2.0.ZU;2-H
Abstract
Photolysis of Cp*Fe(CO)(2)Me in the presence of BH3. PMe3 (1) produced a bo ryliron complex Cp*Fe(CO)(2)(BH2. PMe3) (2a). Complex 2a and the ruthenium analogue Cp*Ru(CO)(2)(BH2. PMe3) (3) were accessible by the salt-eliminatio n reaction between K[Cp*M(CO)(2)] (M = Fe, Ru) and BH2Cl . PMe3.