Vp. Bruskov et al., Synthetic analogs of Peganum alkaloids VIII. A quantum-mechanical investigation of the reduction of deoxypeganine and its derivatives, CHEM NAT CO, 35(2), 1999, pp. 196-200
The alkaloid deoxypeganine and some of its derivatives have been subjected
to reduction with sodium tetrahydroborate and with the complex NaBH4. BF3.
Et2O. It has been shown that the structures of the reduction products depen
d on the presence and positions of substituents in the benzene ring. The qu
antum-chemical calculations performed have confirmed the probable formation
of reduced structures of the type of o-aminobenzylpyrrolidine and the type
of a macrocyclic diamine.