Electrocatalytic hydrogenation of olefins using palladium metal microparticles deposited on viologen film-coated graphite felt

Authors
Kashiwagi, Y Shibayama, N Anzai, J Osa, T
Citation
Y. Kashiwagi et al., Electrocatalytic hydrogenation of olefins using palladium metal microparticles deposited on viologen film-coated graphite felt, ELECTROCH, 68(1), 2000, pp. 42-45
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
ELECTROCHEMISTRY
ISSN journal
13443542 → ACNP
Volume
68
Issue
1
Year of publication
2000
Pages
42 - 45
Database
ISI
SICI code
1344-3542(200001)68:1<42:EHOOUP>2.0.ZU;2-Q
Abstract
Palladium (Pd) metal microparticles were deposited in a viologen-containing polymer layer on the surface of a graphite felt electrode. The Pd-deposite d electrode is effective for the electrocatalytic hydrogenation of the carb on-carbon double bond part of alkyl olefins (1-hexene, 1-decene, cis-2-pene tene), conjugated enones (2-cyclohexene-1-one, 4-isopropyl-2-cyclohexene-1- one, 3,5,5-trimetyl-2-cyclohexene-1-one), styrene, and trans-stilbene with 100 % selectivity.