Preparation and a novel rearrangement reaction of 1,2,3, 4-tetrahydro-9-hydroxy-beta-carboline, and their applications for the total synthesis of (+/-)-coerulescine

Authors
Somei, M Noguchi, K Yamagami, R Kawada, Y Yamada, K Yamada, F
Citation
M. Somei et al., Preparation and a novel rearrangement reaction of 1,2,3, 4-tetrahydro-9-hydroxy-beta-carboline, and their applications for the total synthesis of (+/-)-coerulescine, HETEROCYCLE, 53(1), 2000, pp. 7-10
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
53
Issue
1
Year of publication
2000
Pages
7 - 10
Database
ISI
SICI code
0385-5414(20000101)53:1<7:PAANRR>2.0.ZU;2-R
Abstract
Novel 9-hydroxy-beta-carboline derivatives were produced for the first time . A novel rearrangement reaction of 1,2,3,4-tetrahydro-9-hydroxy-beta-carbo lines was discovered to give 3,3-disubstituted oxindoles, which was success fully applied to the total synthesis of (+/-)-coerulescine.