It is common practice in state estimation of chemical systems to include au
gmented states modeled as random-constant or random-walk processes. When pr
ocess controllers with integral terms are present, undesirable interaction
effects may occur between the augmented states and the controllers. If no a
ttention is paid to this interaction, the resulting estimator may diverge.
In this work the interaction between controller and augmented states is ana
lyzed. Using the linear systems theory, it is shown that the unwanted inter
action and final divergence are caused by lack of detectability of the augm
ented system. A specific test, based on the Popov-Belevitch-Hautus rank tes
t, to check the detectability in the system under study is derived. In many
cases the test can be performed by simple inspection. A series of examples
are given where the concept of detectability is applied to help in discove
ring and preventing the negative interaction between controllers and augmen
ted states. Finally, a discussion is presented comparing the results of the
standard observability test, applied to a real problem, with those obtaine
d with the test derived here and with the behavior of a real estimator for
the same problem. It is concluded that the standard observability test is n
ot able to discriminate between different estimator designs and consequentl
y to produce practical results as those obtained with the alternative test,
i.e., the disclosure of unfeasible estimator designs.