Tris(trifluoromethyl)germanium iodide as a new cross-linking agent in the synthesis of clathrochelates: monomeric mono- and binuclear iron(II) complexes formed by capping with germanium(IV)

Authors
Voloshin, YZ Varzatskii, OA Strizhakova, NG Tkachenko, EY
Citation
Yz. Voloshin et al., Tris(trifluoromethyl)germanium iodide as a new cross-linking agent in the synthesis of clathrochelates: monomeric mono- and binuclear iron(II) complexes formed by capping with germanium(IV), INORG CHIM, 299(1), 2000, pp. 104-111
Citations number
31
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
299
Issue
1
Year of publication
2000
Pages
104 - 111
Database
ISI
SICI code
0020-1693(20000228)299:1<104:TIAANC>2.0.ZU;2-Z
Abstract
The first monomeric mono- and binuclear clathrochelates with trifluoromethy lgermanium-containing capping groups have been prepared by template condens ation of cyclohexanedion-1,2-dioxime, diacetylazineoxime and diacetylmonoxi me hydrazone with IGe(CF3)(3) on an Fe2 + ion. The trigonal-antiprismatic g eometry at the Fe2 + coordination polyhedron for the complexes obtained has been established from Fe-57 Mossbauer and UV spectra. (C) 2000 Elsevier Sc ience S.A. All rights reserved.