Some electrode materials for intermediate temperature proton-conducting fue
l cells are analysed from the perspective of surface reaction and ionic con
ductivity type. The performance of H-2/O-2 fuel cells using these materials
as electrodes with LiNaSO4-Al2O3 as the electrolyte indicates that Ni-Al a
lloy, Ni-Al2O3 catalyst and Ni-YSZ cermet are potential candidates for anod
e materials and that LiNiO2, LiCoO2, Ag-SnO2 and La0.8Sr0.2MnO3 are good ca
ndidates for cathode materials. Among the tested electrode materials, for t
he same electrolyte, the LiNiO2/Ni-Al2O3 electrode pair gives the best cell
performance.