Electrosynthesis of hydrogen peroxide by partial reduction of oxygen in alkaline media. Part II: Wall-jet ring disc electrode for electroreduction ofdissolved oxygen on graphite and glassy carbon

Citation
P. Ilea et al., Electrosynthesis of hydrogen peroxide by partial reduction of oxygen in alkaline media. Part II: Wall-jet ring disc electrode for electroreduction ofdissolved oxygen on graphite and glassy carbon, J APPL ELEC, 30(2), 2000, pp. 187-192
Citations number
33
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED ELECTROCHEMISTRY
ISSN journal
0021891X → ACNP
Volume
30
Issue
2
Year of publication
2000
Pages
187 - 192
Database
ISI
SICI code
0021-891X(200002)30:2<187:EOHPBP>2.0.ZU;2-9
Abstract
A wall-jet ring disc electrode was constructed by adapting a wall-jet flow through electrochemical cell. Commercially available spectral graphite and glassy carbon were used as working disc electrodes and the ring electrode w as made of stainless steel. The efficiency and rate constants, measured in a planar parallel flow hydrodynamic regime, indicated the partial electrore duction of dissolved oxygen as a quasi-reversible two-electron process for both electrode materials tested.