Electrochemical reduction of NO and O-2 on Cu/CuO

Citation
Kk. Hansen et al., Electrochemical reduction of NO and O-2 on Cu/CuO, J APPL ELEC, 30(2), 2000, pp. 193-200
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED ELECTROCHEMISTRY
ISSN journal
0021891X → ACNP
Volume
30
Issue
2
Year of publication
2000
Pages
193 - 200
Database
ISI
SICI code
0021-891X(200002)30:2<193:ERONAO>2.0.ZU;2-4
Abstract
The electrochemical reduction of NO and O-2 on a Cu-point electrode covered with a surface layer of CuO is investigated in an electrochemical cell wit h a gadolinium doped cerium oxide oxygen ion conducting electrolyte in the temperature interval 300-500 C-degrees. It is shown that the reduction of N O on CuO is possible at a lower overvoltage than it is in the case of the r eduction of O-2. The results indicate that the reduction of NO on CuO is no t inhibited in the presence of O-2 and that the reduction of NO can be sele ctively performed on a CuO-electrode.