Electrical conductivity of concentrated aqueous mixtures of HCl and KCl ina wide range of compositions and temperatures

Citation
A. Usobiaga et al., Electrical conductivity of concentrated aqueous mixtures of HCl and KCl ina wide range of compositions and temperatures, J CHEM EN D, 45(1), 2000, pp. 23-28
Citations number
36
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
1
Year of publication
2000
Pages
23 - 28
Database
ISI
SICI code
0021-9568(200001/02)45:1<23:ECOCAM>2.0.ZU;2-#
Abstract
The electrical conductivity of the HCl + KCl + H2O ternary system has been measured in a wide range of compositions (0 mol.dm(-3) < c(HCl) < 6 mol.dm( -3) and 0 mol.dm(-3) < c(KCl) < 1.2 mol.dm(-3)) and temperatures (15 degree s C < t < 45 degrees C) making use of an automated station for conductometr ic titration based on the "electrodeless conductivity" technique. The exper imental data obtained have been fitted to a polynomial in the HCl molar con centration, the KCl molar concentration, and the temperature. As a result, an empirical model enabling the interpolation of the conductivity of the ch emical system under study within the limits of the variables investigated h as been proposed.