Solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide

Citation
Y. Yamini et N. Bahramifar, Solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide, J CHEM EN D, 45(1), 2000, pp. 53-56
Citations number
16
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
45
Issue
1
Year of publication
2000
Pages
53 - 56
Database
ISI
SICI code
0021-9568(200001/02)45:1<53:SOPAHI>2.0.ZU;2-O
Abstract
The equilibrium solubilities of three solid polycyclic aromatic hydrocarbon s (acenaphthene, fluoranthene, and triphenylene) were determined at tempera tures ranging from 308 K to 348 K and pressures from 121.6 to 354.6 bar in supercritical CO2. The data were obtained by using a simple static sampling apparatus which was tested by measuring the solubility of naphthalene in c ompressed CO2. The measured solubilities were correlated using a semiempiri cal model. The calculated results show satisfactory agreement with the expe rimental data.