We present a novel technique to grow AIN on sapphire heteroepitaxially by t
he use of high-density active nitrogen species, which are generated at the
resonance point of nitrogen-ECR plasma? where metal Al is evaporated The Al
N film having the c-axis perpendicular to the c-plane of sapphire was obtai
ned at the growth rate of 0.5 mu m/h with the substrate temperature lower t
han 600 degrees C. The him had the band gap energy of 6.0 eV and good Raman
selection rules. (C) 2000 Elsevier Science B.V. All rights reserved.